MATERIAL SAFETY DATA SHEET
I. PRODUCT IDENTIFICATION
Manufacturer/Supplier:
ESPI Metals
1050 Benson Way, Ashland, OR 97520
Toll Free (800) 638-2581 * Fax (541) 488-8313
E-Mail: sales@espimetals.com
Trade Name: Lutetium Oxide
Synonyms: Lutetium trioxide
Formula: Lu2O3
CAS #: 12032-20-1
II. HAZARDOUS INGREDIENTS
Hazardous Component: Lutetium Oxide
%: 0-100
OSHA/PEL: N/E
ACGIH/TLV: N/E
HMIS Ratings: Health: 2 Flammability: 0 Reactivity: 0
III. PHYSICAL DATA
Boiling Point: N/A
Melting Point: 2487 oC
Specific Gravity: 9.42 g/cc
Vapor Density: N/A
% Volatiles: N/A
Solubility in H2O: Insoluble
Appearance and Odor: White powder, no odor
IV. FIRE AND EXPLOSION HAZARDS DATA
Flash Point: N/A
Flammability: Non-flammable
Autoignition Temperature: N/A
Flammable Limits: Upper: N/A Lower: N/A
Extinguishing Media: Use suitable extinguishing media for surrounding material and type of fire.
Special Firefighting Procedures: Firefighters must wear full face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes.
Unusual Fire & Explosion Hazard: When heated to decomposition, lutetium oxide may emit toxic fumes.
V. HEALTH HAZARD INFORMATION
Effects of Exposure:
To the best of our knowledge the chemical, physical and toxicological properties of lutetium oxide have not been thoroughly investigated and recorded.
Lutetium is considered a rare earth metal. These metals are considered moderately to highly toxic. The symptoms of toxicity of the rare earth elements include writhing, ataxia, labored respiration, walking on the toes with arched back and sedation. The rare earth elements exhibit low toxicity by ingestion exposure, moderate toxicity by subcutaneous exposure and high toxicity by intraperitoneal exposure. Extensive protection is required to prevent the production of skin and lung granulomas.
Acute Effects:
Inhalation: May cause irritation to the respiratory tract and mucous membrane. Dusts may cause asthma attacks and lung damage such as lung granulomas. Large doses may cause writhing, loss of muscle coordination, labored respiration, sedation, hypotension and cardiovascular collapse.
Ingestion: May cause gastrointestinal irritation.
Skin: May cause irritation, rashes and skin granulomas.
Eye: May cause irritation.
Chronic Effects:
Inhalation: Prolonged or repeated inhalation may cause writhing, loss of muscle coordination, labored respiration, sedation, hypotension and cardiovascular collapse.
Ingestion: May affect the coagulation rate of the blood.
Skin: May cause dermatitis, sensitivity to heat, itching and skin lesions.
Eye: No chronic health effects recorded.
Medical Conditions Generally Aggravated By Exposure: Pre-existing respiratory disorders.
Carcinogenicity: NTP: No IARC: No OSHA: No
EMERGENCY AND FIRST AID PROCEDURES:
INHALATION: Remove to fresh air, keep warm and quiet, give oxygen if breathing is difficult and seek medical attention.
INGESTION: Give 1-2 glasses of milk or water and induce vomiting, seek medical attention. Never induce vomiting or give anything by mouth to an unconscious person.
SKIN: Remove contaminated clothing, brush material off skin, wash affected area with soap and water, seek medical attention if irritation persists.
EYES: Flush eyes with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes. Seek medical attention if irritation persists.
VI. REACTIVITY DATA
Stability: Stable
Conditions to Avoid: Water/moisture
Incompatibility (Material to Avoid): Strong acids
Hazardous Decomposition Products: None recorded.
Hazardous Polymerization: Will not occur
VII. SPILL OR LEAK PROCEDURES
Steps to Be Taken in Case Material Is Released or Spilled: Wear appropriate respiratory and protective equipment specified in section VIII. Isolate spill area and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for proper disposal. Take care not to raise dust.
Waste Disposal Method: In accordance with Local, State and Federal Waste Disposal Regulations.
VIII. SPECIAL PROTECTION INFORMATION
Respiratory Protection: NIOSH approved dust respirator.
Ventilation: Use local exhaust to maintain concentration of exposure at low levels. General exhaust is recommended.
Protective Gloves: Rubber Gloves
Eye Protection: Safety Glasses
Other Protective Clothing or Equipment: Protective gear suitable to prevent contamination.
IX. SPECIAL PRECAUTIONS
Precautions to Be Taken in Handling and Storage: Store in a cool, dry area. Store in tightly sealed container. Wash thoroughly after handling.
Other Precautions: Hygroscopic. Protect from moisture.
Work Practices: Implement engineering and work practice controls to reduce and maintain concentration of exposure at low levels. Use good housekeeping and sanitation practices. Do not use tobacco or food in work area. Wash thoroughly before eating and smoking. Do not blow dust off clothing or skin with compressed air. Maintain eyewash capable of sustained flushing, safety drench shower and facilities for washing.
DOT Regulations:
Hazard Class: None
The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide. ESPI shall not be held liable for any damage resulting from handling or from contact with the above product.
Issued by: S. Dierks
Issue Date: May 2007